As noted, WWE is working on a new DVD/Blu-ray compilation (not officially named yet) on Randy Orton that will be released on November 14th in the UK, and on November 15th in the US.
Courtesy of Wrestling DVD Network, here is the full content listing for the DVD:
DISC 1
Randy Orton vs. Johnny Spade – OVW • June 24, 2000
Randy Orton vs. Flash Flanagan – RAW [Un-Televised]• April 16, 2001
Randy Orton vs. Prototype – OVW • June 16, 2001
WWE Undisputed Championship Match: Undertaker vs. Randy Orton – SmackDown • May 30, 2002
6-Man Elimination Tag Team Match: Dudley Boyz vs. Evolution – RAW • July 14, 2003
Intercontinental Championship Match: Chris Jericho vs. Randy Orton – RAW • July 5, 2004
Intercontinental Championship Match: Edge vs. Randy Orton – RAW • July 19, 2004
Randy Orton vs. Triple H – RAW [Un-Televised] • December 13, 2004
DISC 2
D-Generation X vs. Rated RKO – Cyber Sunday • November 5, 2006
WWE Championship Match: Shawn Michaels vs. Randy Orton – Survivor Series • November 18, 2007
WWE Championship Match: Jeff Hardy vs. Randy Orton – Royal Rumble • January 27, 2008
Last Man Standing Match: Randy Orton vs. CM Punk – Extreme Rules • May 1, 2011
Randy Orton vs. Dolph Ziggler – RAW • August 29, 2011
DISC 3
Steel Cage Match for the World Heavyweight Championship: Randy Orton vs. Christian – SmackDown • August 30, 2011
Money in the Bank Ladder Match: CM Punk vs. Sheamus vs. Daniel Bryan vs. Randy Orton vs. Christian vs. Rob Van Dam – Money in the Bank • July 14, 2013
TLC Unification Match for the WWE World Heavyweight Championship: John Cena vs. Randy Orton – Tables, Ladders, Chairs • December 15, 2013
Randy Orton vs. Dean Ambrose – RAW • July 7, 2014
Randy Orton vs. Seth Rollins – WrestleMania 31 • March 29, 2015
#1 Contenders Triple Threat Match: Randy Orton vs. Kevin Owens vs. Cesaro – RAW • August 10, 2015
BLU-RAY EXCLUSIVES
Intercontinental Championship Match: Randy Orton vs. Shelton Benjamin – Bad Blood • June 13, 2004
No Holds Barred Match for the World Heavyweight Championship
Randy Orton vs. Christian – SummerSlam • August 14, 2011
Randy Orton vs. Damien Sandow – NXT • March 27, 2013
Randy Orton & Team Hell No vs. The Shield – SmackDown • June 14, 2013